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CHEMets® Water Test Kits

Document Number: 1200
The CHEMets® system employs vacuum
sealed, self-filling ampoules for colorimetric analysis. Each ampoule
contains a premixed, premeasured unit dose of reagent to run one test.
Vacuum sealing insures that when the tip is snapped, the correct volume of
sample is drawn into the ampoule to mix with the reagent. The resulting
color change is compared with color standards supplied with each kit. The
results are quantitative and are usually ready in 2 minutes or less. All
test methods are based on USEPA, ASTM and APHA standard procedures and
chemistries.
Test Procedure
The CHEMets® ampoule is immersed in the
sample and the tip is snapped off using the specially designed snap cup. The
correct volume of sample is drawn in. A small inert gas bubble will form. Mix
the sample and reagent by tilting the ampoule several times so the bubble
travels from end to end. In 2 minutes or less, the resulting color change is
compared to the appropriate color standards to quantify the result. Depending on
the test kit, one or two comparators will be provided:
Low Concentrations: Less than 1 ppm. In most cases the cylindrical
comparator is used to quantify low concentrations. The test ampoule is placed in
the center of the comparator and compared with the eight color standards around
it.
Medium Concentrations: Above 1 ppm. The flat comparator is usually
used for these concentrations. The filled ampoule is placed between standards
until a color match is found.
Testing Methods
Ammonia (nitrogen)
ASTM Vol. 11.01 Water (I), p. 380, method D 1426, part, A (1993). APHA
Standard Methods, 18th ed., p. 4-78, method 4500-NH3 C (1992).
Test results are determined by direct Nesslerization. Concentration is directly
proportional to the intensity of the yellow color formed. A stabilizer solution
is added if the test water contains sufficient concentrations of calcium and
magnesium to cloud the reagent. The test has a shelf-life of 5 months.
Refrigeration will double the shelf-life of the kits.
Chlorine (free & total) DPD method
EPA Methods for Chemical Analysis of Water and Wastes, method 330.5
(1983).
Free chlorine reacts with DPD to form a red color. The intensity of the pink color is directly proportional to the concentration of chlorine in the sample.
When ammonia or amines are present, some of the chlorine may exist as combined
chlorine, which will not interfere with the free chlorine results, provided the
reading is taken at 1 minute. The activator solution provided is used to
determine total chlorine.
Iron (total and soluble)
APHA Standard Methods, 18th ed., p. 3-66, method 3500-Fe D (1992) ASTM Part
31 on Water, p. 445, method D-1068 part A (1981).
To determine total iron, thioglycolic acid reduces ferric iron to the ferrous
state, which then reacts with 1, 10-phenanthroline in acid solution to form a
red colored chelate. The intensity of the color is directly proportional to the
iron concentration in the sample. The reagents are formulated to compensate for
interference from oxidizing agents. To determine soluble iron only, do not use
the activator solution.
Nitrate (nitrogen)
ASTM Vol. 11.01 Water (I), p. 583, method D 3867, part B (1993). APHA
Standard Methods, 18th ed., p. 4-89, method 4500-NO3-E (1992). EPA Methods for
Chemical Analysis of Water and Wastes, method 353.3 (1983).
Nitrate is reduced to nitrite using cadmium as the reducing agent. The nitrite
concentration is then determined by the intensity of the resulting pink color.
The color of the pink azo dye is directly proportional to the nitrite
concentration of the sample. Nitrite will interfere with this test.
Oxygen (dissolved)
Indigo Carmine-ASTM Part 31 on Water, p. 530, method A (1981)
The reduced form of indigo carmine reacts to form a blue color. The intensity of
the blue color is directly proportional to the D.O. concentration in the sample.
The indigo carmine test is not influenced by temperature, salinity or dissolved
gases, which affect D.O. meters.
Phosphate (reactive, ortho)
Stannous chloride-APHA Standard Methods, 18th ed., p. 4-114, method 4500-P D
(1992). This test method measures "ortho" or reactive phosphate, which
is usually termed "ortho-phosphate".
The test uses the molybdenum blue method with stannous chloride reduction.
Phosphate reacts with ammonium molybdate and is then reduced by stannous
chloride to form a blue complex. The intensity of the color is directly
proportional to the phosphate concentration in the sample.
Specifications:
| Test |
Range |
Comparator Increments
(some kits have 2 ranges) |
Analysis Time (min.) |
| Dissolved Oxygen-O2 |
1-12 ppm |
1, 2, 3, 4, 5, 6, 8, 10, 12 ppm |
2 |
| Chlorine (free
and total)-Cl2 |
0-1 ppm |
0.1, 0.2, 0.3,
0.4, 0.6, 0.8, 1.0 ppm |
|
| |
1-5 ppm |
1.0, 1.5, 2.0,
2.5, 3.0, 3.5, 4.0, 4.5, 5.0 ppm |
2 |
| Nitrate (nitrogen)-NO3-N |
0-25 ppm |
0, 2.5, 5.0, 7.5, 10, 15, 20, 25
ppm |
|
|
25-125 ppm |
25, 27.5, 50, 62.5, 75, 87.5,
100, 112.5, 125 ppm |
11 |
| Phosphate-PO4 |
0-1 ppm |
0, 0.1, 0.2,
0.3, 0.4, 0.6, 0.8, 1.0 ppm |
|
| |
1-10 ppm |
1, 2, 3, 4, 5,
6, 7, 8, 9, 10 ppm |
3 |
| Iron (total and soluble)-Fe |
0-1 ppm |
0, 0.1, 0.2, 0.3, 0.4, 0.6, 0.8,
1.0 ppm |
|
|
1-10 ppm |
1, 2, 3, 4, 5, 6, 7, 8, 9, 10 ppm |
1 |
| Ammonia
(nitrogen)-NH3-N |
0-1 ppm |
0, 0.1, 0.2,
0.3, 0.4, 0.6, 0.8, 1.0 ppm |
|
| |
1-10 ppm |
1, 2, 3, 4, 5,
6, 7, 8, 9, 10 ppm |
2 |
Ordering Information
| Item Number |
Description |
| 225480 |
Dissolved Oxygen Test Kit |
| 225481 |
Dissolved Oxygen Refill |
| 225482 |
Chlorine Test Kit |
| 225483 |
Chlorine Refill |
| 225484 |
Nitrate (Nitrogen) Test Kit |
| 225485 |
Nitrate (Nitrogen) Refill |
| 52891 |
Phosphate Test Kit |
| 52892 |
Phosphate Refill |
| 52887 |
Iron (Total and Soluble) Test Kit |
| 85350 |
Iron (Total and Soluble) Refill |
| 16806-1 |
Ammonia (Nitrogen) Test Kit |
| 16806-2 |
Ammonia (Nitrogen) Refill |
FREE Technical Support
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applications or installation, personal safety gear, regulatory
compliance requirements, or any other technical questions E-mail
our Technical Support staff. Or, call 800-241-6401 or 608-743-8001 from 7 a.m. to
5 p.m. CT, Monday--Friday.
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Please Note: The information contained in this
publication is intended for general information purposes only. This
publication is not a substitute for review of the applicable government
regulations and standards, and should not be construed as legal advice
or opinion. Readers with specific questions should refer to the cited
regulation or consult with an attorney.
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